- Type
- Raman scattering
- Assignments summary
- Characteristics summary
| Assignment | Symmetry | Mode | Specie(s) | Molecule/Atom | Bond | Multiplicity | Degeneracy | Contribution | Resonance |
|---|---|---|---|---|---|---|---|---|---|
| 2ν2 (A1g) | A1g | deformation out-p | (CO3)2- | (CO3)2- | no | full |
| Peak position (cm-1) |
Center position (cm-1) |
Width (cm-1) |
Shape | Asymmetry factor | Peak intensity (cm-1) |
Peak intensity relative | Peak strength | Integrated intensity (cm-2) |
Integrated intensity relative | Integrated strength | Temperature (K) |
Pressure (bar) |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1734 ± 8 | - | 21.75 ± 3.75 | asymmetric | 0.021 | w | 0.053 | w | 295.0 | 1 |
- Label
- 2ν2 (A1g)
- Symmetry
- A1g
- Category
- overtone vibration
Evaluation
- Level
- fully assigned
- Evaluation
- validated
- Contribution level
- full
| # | Multiplicity type | Degeneracy | Other band |
|---|---|---|---|
| 1 | no |
- Primary specie
- (CO3)2-
- Label (type)
- 2ν2 (deformation out-p) Bond: (CO3)2-
- Comments
- O-C-O out-of-plane deformation overtone
Vibration modes
- Composition
- 0.05
- Texture
- crystal in plot
- Temperature
- 295.0 ± 5.0 K
Temperature
- Pressure
- 1 bar
Pressure
- Laser wavelength
- 532.0 nm
- Sample orientation mode
- unoriented
- Method #1
- various
- Overlap
- isolated
- Peak
- 1734 ± 8 cm-1 (fit peak)
- Evaluation
- validated
- Quality
- D
- Comments
- increases with Mg fraction
- FWHM
- 21.75 ± 3.75 cm-1 (fit fwhm)
- Shape
- asymmetric
- Evaluation
- validated
- Quality
- D
- Comments
- weak low frequency shoulder - increases with Mg fraction
- Method
- baseline corrected peak intensity
- Relative intensity
- 0.021 ± 0.005
- Strength
- weak (w)
- Evaluation
- validated
- Quality
- D
- Comments
- decreases with Mg fraction
- Method
- width x peak intensity
- Relative intensity
- 0.053 ± 0.004
- Strength
- weak (w)
- Evaluation
- recommended
- Quality
- C
- Publication
- SSHADE spectra
-
- Schmitt, Bernard; Montagnac, Gilles (2025): MIR-FIR normalized Raman spectrum (532 nm) of Mg-Mn-Siderite (St-Georges d'Hurtières) - grain M2-F1 - Mg# = 7.65%. Version 1. SSHADE/DRIMS (OSUG Data Center). Dataset/Spectral Data.
- Schmitt, Bernard; Montagnac, Gilles (2025): MIR-FIR normalized Raman spectrum (532 nm) of Mg-Siderite (Terril du Villaret, France) - grain M4-H0 - Mg# = 24.7%. Version 1. SSHADE/DRIMS (OSUG Data Center). Dataset/Spectral Data.
- Schmitt, Bernard; Montagnac, Gilles (2025): MIR-FIR normalized Raman spectrum (532 nm) of Mg-Siderite (Mines de La Mure, France) - grain M3-E8a - Mg# = 39.2%. Version 1. SSHADE/DRIMS (OSUG Data Center). Dataset/Spectral Data.